May 13, 20202 min read

New dispersing agent for PR57.1

Updated: Nov 23, 2023

When a drop of liquid is placed on a surface it can either:

Spread over the surface – it therefore ‘wets’
Form a stable drop – it is unable to ‘wet’

Reduction in surface tension of water by addition of a surfactant can make a non-wetting solution into a wetting solution on particular substrates. The ability to wet or not depends upon the surface tension of the solution and the critical surface tension (CST) or surface energy of the solid. The CST is the surface tension of a liquid which will form a contact angle of close to zero measured across the film on that solid, i.e. the liquid spreads over the solid. Glass, with a CST of more than 70 dynes/cm can be wet easier than polypropylene, with a CST of 28. In all cases to wet a substrate quickly and effectively, a surfactant will be required to help reduce the surface tension and overcome the surface energy of the substrate.

The surface energy of different substrates vary. High energy substrates are easier to wet than low energy substrates.

The diagram below shows the relationship between the surface tension of a droplet onto a substrate surface and the contact angle. The shape of a liquid-vapour interface is determined by the Young–Dupre equation, with the contact angle playing the role of a boundary condition via the Young equation.

The simplified equation is: cos Θc = ϒSL – ϒSG / ϒLG ϒSL = Solid–liquid interfacial energy ϒSG = Solid–vapour interfacial energy ϒLG = Surface tension

The conclusions that can be drawn are:

A substrate with high surface tension is easily wetted
A liquid with a low surface tension wets a substrate easily

In all cases to wet a substrate quickly and effectively, a surfactant will be required to help reduce the surface tension of the droplet or liquid low enough to overcome the surface energy of the substrate.

Surface Energy of Substrates

Substrate	Surface Energy - mN/m
Copper	~ 1000
Aluminium	~ 500
Glass	290
Stainless steel	53
Lino	~45
Polycarbonate	44
Nylon 6	43.9
Nylon 66	42.2
PET G	39
Rigid PVC	37.9
PE 1000	31.6
Acetal	31
Polypropylene	30.5
PTFE	19.4

Static contact angle measurement

One of the most popular ways of measuring contact angles is using the ‘Sessile Drop Technique’. The contact angle of a sessile drop resting on a solid surface is measured using a goniometer. The goniometer is connected to a microscope and video camera.

The drop of the prepared test liquid is released through a fine needle and allowed to drop under gravity onto the substrate whilst filming the action. From the captured image as seen in the first image above the contact angle can be measured either manually or by utilizing the software.

Sessile Drop A Typical Goniometer

Experimental work on various substrates

Below will highlight of the programme of work that we have carried out on various substrates and substances.

Several test liquids were prepared as a 0.5% solution in deionised water and some test substrates consisting of different plastics and metals were utilised.

An FTȦ 200 goniometer equipped with a digital microscope and video capture was used to analyse the sessile drop images.

A detailed list of substrates tested and their recommendations:

Substrate	1st Choice	Biobased
Acetal	Lanwet JH1	Bioloop 56L or T48
Acrylic Sheet	Lanwet JH1	Bioloop 56L or T48
Aluminium	Lanwet JH1	Bioloop 56L
Copper	Lanwet JH1
Galvanised Steel	Lanwet JH1
Glass	Lanwet JH1	Bioloop 84L or T45
Karndean	Lanwet JH1
Lino	Lanwet JH1
Nylon 6	Lanwet JH1	Bioloop 68L or T25
Nylon 66	Lanwet JH1	Bioloop 56L, T25 or T48
PE 1000	Lanwet JH1
PET G	Lanwet JH1	Bioloop 56L
Polycarbonate	Bioloop 56L	Bioloop 56L or 68L
Polypropylene	Lanwet JH1	Bioloop 56L
PTFE	Lanwet JH1
Rigid PVC	Lanwet JH1
Stainless steel	Lanwet JH1
Vinyl Flooring	Lanwet JH1	Bioloop T65